The award-winning host continues his anarchic talk show. He is joined by Mad Men's Don Draper himself, Jon Hamm; actress Charlize Theron; and Alan Partridge alter-ego Steve Coogan.

James McAvoy talks about working with Bruce Willis, Sarah Paulson reveals how she got Samuel L Jackson to like her, Richard E Grant celebrates losing his awards virginity, Steve Coogan and John C Reilly talk about friendship and Westlife perform live in the studio.